Quantum mechanics/Rigid rotor
It is a well known result of classical mechanics that a system with only two particles (with coordinates x1, y1, z1 and x2, y2, z2 and masses m1 and m2) can be described in terms of the relative positions between the two particles, i.e. using the coordinates x = x1 - x2, y = y1 - y2, z = z1 - z2. To do so you have to used the reduced mass of the system μ = m1m2 ÷ (m1 + m2). Intuitively it is like sitting on one of the particles (e.g. the nucleus of a hydrogen atom) and seeing the motion of the other from that point of view.
Potential only dependent on the distanceEdit
Consider two particles whose interaction depends only on the distance r between them. The Hamiltonian for such a system is
It makes sense to use polar coordinates in this case. The partial derivatives of the kinetic energy operator take the following form when expressed in polar coordinates:
It is customary to give a special symbol to the operator in the square brackets and involving all the angular variables:
The Schrödinger equation for two particles whose potential energy only depends on the distance between them is therefore:
We will consider two important cases: the rigid rotor, and the hydrogen atom.
Consider two particles with reduced mass μ whose distance is fixed to the value R. This is named a rigid rotor and is a model for the rotation in space of a biatomic molecule (if we neglect its vibration). Equation 4 becomes:
which is obtained by removing all derivatives with respect to r and ignoring V(r). Equation 5 also represents the motion of a particle with mass μ constrained on a sphere of radius R.
The eigenvalues and eigenfunctions of equation 5 will be presented without proof as their calculation is too complicated. They are called spherical harmonics, and are indicated as Ylm(θ, Φ)
The spherical harmonics depend on two quantum numbers:
- l - the orbital angular momentum quantum number
- m - the magnetic quantum number
l can take the values 0,1,2,... . m can take values that depend on l: m=l,l-1,...,-l
The eigenvalues depend only on the quantum number l.
I = μR2 is the moment of inertia. For each quantum number l, there are 2l+1 different wavefunctions (one for each value of m) with the same energy, i.e. that are degenerate. The level with quantum number l has degeneracy 2l+1. The eigenfunctions have the following form:
Nlm is a normalization constant. Θlm(θ) is a polynomial of cos(θ) and sin(θ) which depends on both quantum numbers l and m. Φm = eimφ is identical to the wavefunction of the particle in a ring.
Classical and quantum angular momentumEdit
The total energy of a classical rigid rotor is where L2 is the square of the total angular momentum. By comparison with Equation 6 we can argue that the quantum angular momentum is quantized as L2 ↔ ħ2l(l+1). We have already seen that the projection of the angular momentum on the z axis is related to the quantum number m as Lz ↔ ħm.
Next: Lesson 7 - The Hydrogen Atom